1-Cyclopropylethanol → HCID 11327513, compound

HRID 2165797Notes

Reaction equation

[Cl:1][C:2]1[CH:10]=[CH:9][C:8]([N:11]2[C:16](=[O:17])[CH:15]=[C:14]([C:18]([F:21])([F:20])[F:19])[N:13]([CH3:22])[C:12]2=[O:23])=[CH:7][C:3]=1[C:4]([OH:6])=[O:5].[CH:24]1([CH:27](O)[CH3:28])[CH2:26][CH2:25]1>>[Cl:1][C:2]1[CH:10]=[CH:9][C:8]([N:11]2[C:16](=[O:17])[CH:15]=[C:14]([C:18]([F:20])([F:19])[F:21])[N:13]([CH3:22])[C:12]2=[O:23])=[CH:7][C:3]=1[C:4]([O:6][CH:27]([CH:24]1[CH2:26][CH2:25]1)[CH3:28])=[O:5]

Participants

Reactant 2

HCID 791041-Cyclopropylethanol

HCID 21933503Flupropacil acid

Product 1

HCID 11327513HCID 11327513, compound

Procedure

In an analogous manner, starting from 2-chloro-5-[3,6-dihydro-2,6-dioxo-3-methyl-4-trifluoromethyl-1(2H)-pyrimidinyl]-benzoic acid via its acid chloride and 1-cyclopropylethanol there is obtained 1-cyclopropylethyl 2-chloro-5-[3,6-dihydro-2,6-dioxo-3-methyl-4-trifluoromethyl-1(2H)-pyrimidinyl]-benzoate, m.p. 118°-119° C.;

Sources & evidence

ORD record: ord-b615f694eae342abbac8c1407a9bd625
Source dataset: uspto-grants-1990_07
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04941909

Reaction notes

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