Benzenepropanoic acid, 4-hydroxy-, methyl ester → HCID 15616993, compound

HRID 2165826Notes

Reaction equation

HRID 2165826 reaction equation
[CH3:1][O:2][C:3](=[O:13])[CH2:4][CH2:5][C:6]1[CH:11]=[CH:10][C:9]([OH:12])=[CH:8][CH:7]=1.COC(=O)C=CC1C=CC(O)=CC=1.[CH2:27](Cl)[CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH:37]([CH3:39])[CH3:38].C(Cl)CCCCCC(C)C>>[CH3:1][O:2][C:3](=[O:13])[CH2:4][CH2:5][C:6]1[CH:11]=[CH:10][C:9]([O:12][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH:37]([CH3:38])[CH3:39])=[CH:8][CH:7]=1

Participants

5

Reactant 4

HCID 79706Benzenepropanoic acid, 4-hydroxy-, methyl esterHCID 92203Methyl p-coumarateHCID 133917251-Chloro-11-methyldodecaneHCID 15918114Isononyl chloride

Product 1

HCID 15616993HCID 15616993, compound

Procedure

1.5 3-(4-isotridecyloxyphenyl)-propionic acid methyl ester (refractive index at 20° C. : 1.4902) was prepared from 3-(4-hydroxyphenyl)-propionic acid methyl ester, substituted on an equimolar basis for 4-hydroxycinnamic acid methyl ester, and isotridecyl chloride, substituted on an equimolar basis for isononyl chloride, by the method described in 1.1.

Sources & evidence

ORD record
ord-463c6fda858c4364988d99f108fe9f64
Source dataset
uspto-grants-1990_07
Patent number
US04942174

Reaction notes

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