HRID2166003

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID289410

4-(tetradecyloxy)benzoic acid

C21H34O3

HCID13530950

(2S)-2-Methylbutyl 4-hydroxybenzoate

C12H16O3

HCID14533552

未命名化合物

结构：CCCCCCCCCCCCCCOc1ccc(-c2ccc(C(=O)O)cc2)cc1[N+](=O)[O-]

HCID20043522

未命名化合物

PRODUCTS

生成物

结构：CCCCCCCCCCCCCCOc1ccc(-c2ccc(C(=O)Oc3ccccc3)cc2)cc1[N+](=O)[O-]

HCID86743015

未命名化合物

PROCEDURE

实验过程

The procedure of Example 1 was followed except using 3'-nitro-4'-tetradecyloxybiphenyl-4-carboxylic acid instead of said 4-tetradecyloxybenzoic acid and (S)-2-methylbutyl 4-hydroxybenzoate instead of said (S)-2-methylbutyl 2-chloro-4-hydroxybenzoate. There resulted (S)-2-methylbutyloxycarbonyl]phenyl 3'-nitro-4'-tetradecyloxybiphenyl-4-carboxylate].

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-4a1538fe537c4805b228ab07725754df
来源数据集: uspto-grants-1990_07
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04943386
来源说明: uspto-grants-1990_07

反应 SMILES

[N+:1]([C:4]1[CH:5]=[C:6]([C:25]2[CH:30]=[CH:29][C:28]([C:31]([OH:33])=[O:32])=[CH:27][CH:26]=2)[CH:7]=[CH:8][C:9]=1[O:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])([O-:3])=[O:2].C(O[C:49]1[CH:57]=[CH:56][C:52](C(O)=O)=[CH:51][CH:50]=1)CCCCCCCCCCCCC.OC1C=CC(C(OC[C@@H](C)CC)=O)=CC=1.ClC1C=C(O)C=CC=1C(OC[C@@H](C)CC)=O>>[N+:1]([C:4]1[CH:5]=[C:6]([C:25]2[CH:30]=[CH:29][C:28]([C:31]([O:33][C:49]3[CH:57]=[CH:56][CH:52]=[CH:51][CH:50]=3)=[O:32])=[CH:27][CH:26]=2)[CH:7]=[CH:8][C:9]=1[O:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])([O-:3])=[O:2]