HRID2166238

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID518900

Methyl (4-hydroxyphenyl)acetate

C9H10O3

HCID53869168

未命名化合物

PRODUCTS

生成物

结构：COC(=O)Cc1ccc(OCC(C)=CCc2c(C)c(OC)c(OC)c(OC)c2OC)cc1

HCID86740178

未命名化合物

结构：COc1c(C)c(CC=C(C)COc2ccc(CC(=O)O)cc2)c(OC)c(OC)c1OC

HCID86740179

未命名化合物

PROCEDURE

实验过程

Using 1,2,3,4-tetramethoxy-5-methyl-6-(4-chloro-3-methyl-2-butenyl)benzene and methyl p-hydroxyphenylacetate and following the procedure described above, there were obtained methyl 4-[4-(2,3,4,5-tetramethoxy-6-methylphenyl)-2-methyl-2-butenyloxy]phenylacetate (Compound 15) and 4-[4-(2,3,4,5-tetramethoxy-6-methylphenyl)-2-methyl-2-butenyloxy]phenylacetic acid (Compound 16).

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-9bba58edfb7744eabe71a962f9021ece
来源数据集: uspto-grants-1990_07
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04943645
来源说明: uspto-grants-1990_07

反应 SMILES

[CH3:1][O:2][C:3]1[C:8]([CH2:9][CH:10]=[C:11]([CH3:14])[CH2:12]Cl)=[C:7]([CH3:15])[C:6]([O:16][CH3:17])=[C:5]([O:18][CH3:19])[C:4]=1[O:20][CH3:21].[OH:22][C:23]1[CH:28]=[CH:27][C:26]([CH2:29][C:30]([O:32][CH3:33])=[O:31])=[CH:25][CH:24]=1>>[CH3:1][O:2][C:3]1[C:4]([O:20][CH3:21])=[C:5]([O:18][CH3:19])[C:6]([O:16][CH3:17])=[C:7]([CH3:15])[C:8]=1[CH2:9][CH:10]=[C:11]([CH3:14])[CH2:12][O:22][C:23]1[CH:24]=[CH:25][C:26]([CH2:29][C:30]([O:32][CH3:33])=[O:31])=[CH:27][CH:28]=1.[CH3:1][O:2][C:3]1[C:4]([O:20][CH3:21])=[C:5]([O:18][CH3:19])[C:6]([O:16][CH3:17])=[C:7]([CH3:15])[C:8]=1[CH2:9][CH:10]=[C:11]([CH3:14])[CH2:12][O:22][C:23]1[CH:24]=[CH:25][C:26]([CH2:29][C:30]([OH:32])=[O:31])=[CH:27][CH:28]=1