HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Butanol → 2-(2-hydroxy-5-methylphenyl)benztriazole N-oxide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Butanol | HCID 263 | — |
| Reactant | 2-Nitro-2'-hydroxy-3',5'-bis(tert-amyl)azobenzene | HCID 104111 | — |
| Reactant | HCID 135776351 | HCID 135776351 | — |
| Solvent | 1-Propanol | HCID 1031 | — |
| Product | 2-(2-hydroxy-5-methylphenyl)benztriazole N-oxide | HCID 13214646 | 88% |
Reaction Steps
The same procedure as in Example 1 was repeated, except that n-butanol 80 g was replaced by n-propanol 80 g, and that 2-nitro-2'-hydroxy-3',5'-di-t-amylazobenzene 25.5 g was replaced by 2-nitro-2'-hydroxy-5-methylazobenzene 17.1 g, thus producing 14.1 g of 2-(2-hydroxy-5-methylphenyl)benzotriazole-N-oxide having a melting point of 138° to 140° C. at the yield of 88%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04943637 |
| Source dataset | uspto-grants-1990_07 |
| ORD ID | ord-17de2a58800041a6a9b455a3da1a4bf6 |
| Source note | uspto-grants-1990_07 |