Pyridine → HCID 86744125, compound

HRID 2166447Notes

Reaction equation

HRID 2166447 reaction equation
[CH2:1]([O:17][CH2:18][C:19](=[CH2:31])[CH2:20][O:21][CH2:22][CH2:23][CH2:24][CH2:25][O:26][S:27]([CH3:30])(=[O:29])=[O:28])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16].[N:32]1[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=1>>[CH3:30][S:27]([O-:29])(=[O:28])=[O:26].[CH2:1]([O:17][CH2:18][C:19](=[CH2:31])[CH2:20][O:21][CH2:22][CH2:23][CH2:24][CH2:25][N+:32]1[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]

Participants

3

Reactant 2

HCID 1049PyridineHCID 23039617HCID 23039617, compound

Product 1

HCID 86744125HCID 86744125, compound

Procedure

1-Hexadecyloxy-3-[4-(methanesulfonyloxy)butoxy]-2-methylenepropane (from Preparation 7) (1.6 g) was heated with dry pyridine (50 ml) at 50° C. for 28 hours. Excess pyridine was removed in vacuo. The product was recrystallized from chloroform/acetone.

Workup

  1. customExcess pyridine was removed in vacuo
  2. customThe product was recrystallized from chloroform/acetone

Sources & evidence

ORD record
ord-c399783f788d413bad48d21b87c3ad8e
Source dataset
uspto-grants-1990_07
Patent number
US04945098

Reaction notes

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