Pyridine → HCID 67936864, compound

HRID 2166452Notes

Reaction equation

HRID 2166452 reaction equation
[C:1]([O:18][CH2:19][C:20](=[CH2:33])[CH2:21][O:22][C:23](=[O:32])[CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][Br:31])(=[O:17])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16].[N:34]1[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=1>>[Br-:31].[C:1]([O:18][CH2:19][C:20](=[CH2:33])[CH2:21][O:22][C:23](=[O:32])[CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][N+:34]1[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=1)(=[O:17])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]

Participants

3

Reactant 2

HCID 1049PyridineHCID 23039662HCID 23039662, compound

Product 1

HCID 67936864HCID 67936864, compound

Conditions

Temperature
100 °C

Procedure

1-Hexadecanoyloxy-3-(8-bromooctanoyloxy)-2-methylenepropane (from Preparation 30) (0.80 g) was dissolved in dry pyridine (20 ml) and heated to 100° C. for 8 hours. Excess pyridine was removed in vacuo.

Workup

  1. customExcess pyridine was removed in vacuo

Sources & evidence

ORD record
ord-93bbb62807cc48ee9ee4605bd33eb6d0
Source dataset
uspto-grants-1990_07
Patent number
US04945098

Reaction notes

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