Dibutylamine → 1,1-dibutyl-3-(2,4-dimethylphenyl)urea

HRID 2166524Notes

Reaction equation

HRID 2166524 reaction equation
[CH3:1][C:2]1[CH:7]=[C:6]([CH3:8])[CH:5]=[CH:4][C:3]=1[N:9]=[C:10]=[O:11].[CH2:12]([NH:16][CH2:17][CH2:18][CH2:19][CH3:20])[CH2:13][CH2:14][CH3:15]>CCCCCC>[CH2:12]([N:16]([CH2:17][CH2:18][CH2:19][CH3:20])[C:10]([NH:9][C:3]1[CH:4]=[CH:5][C:6]([CH3:8])=[CH:7][C:2]=1[CH3:1])=[O:11])[CH2:13][CH2:14][CH3:15]

Participants

4

Reactant 2

HCID 8148DibutylamineHCID 52075851-isocyanato-2,4-dimethylbenzene

Product 1

HCID 44263801,1-dibutyl-3-(2,4-dimethylphenyl)urea

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent2×

Procedure

A solution of 4.89 g. of 2,4-dimethylphenylisocyanate in 100 ml. of hexane is added to a solution of 3.48 g. of di(n-butyl)amine in 150 ml. of hexane and the solution is stirred at room temperature for 2 hours and then evaporated. The residual solid is recrystallized from pentane to yield 1,1-di-(n-butyl)-3-(2,4-dimethylphenyl)urea, m.p. 48°-50° C.

Workup

  1. customevaporated
  2. customThe residual solid is recrystallized from pentane

Sources & evidence

ORD record
ord-64fbb0e7b14647619e1eb0c1ad16c3a6
Source dataset
uspto-grants-1983_06
Patent number
US04387105

Reaction notes

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