Benzyl Chloride → 5,7-Dimethyl-4-(phenylmethoxy)-6,8-dioxabicyclo(3.2.1)octane

HRID 2166651Notes

Reaction equation

HRID 2166651 reaction equation
[CH3:1][C:2]12[O:10][CH:6]([CH:7]([CH3:9])[O:8]1)[CH2:5][CH2:4][CH:3]2[OH:11].[CH2:12](Cl)[C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1.O1CCCC(O)C1>>[CH3:1][C:2]12[O:10][CH:6]([CH:7]([CH3:9])[O:8]1)[CH2:5][CH2:4][CH:3]2[O:11][CH2:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1

Participants

4

Reactant 3

HCID 7503Benzyl ChlorideHCID 12256033tetrahydro-2H-pyran-3-olHCID 204982715,7-Dimethyl-4-hydroxy-6,8-dioxabicyclo(3.2.1)octane

Product 1

HCID 155834435,7-Dimethyl-4-(phenylmethoxy)-6,8-dioxabicyclo(3.2.1)octane

Procedure

18A was treated with benzyl chloride, by the procedure described for treatment of 1A, to give 18, as a liquid, b.p.: 145° C., 0.06 Torr.

Sources & evidence

ORD record
ord-1d636fc600564aad82c6dc544f985167
Source dataset
uspto-grants-1983_06
Patent number
US04388104

Reaction notes

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