HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethylformamide → 2,3-Dichloro-4-(p-nitrophenylsulfenyl)anisole
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethylformamide | HCID 6228 | — |
| Reactant | p-Fluoronitrobenzene | HCID 9590 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 2,3-Dichloro-4-methoxybenzene-1-thiol | HCID 15914269 | — |
| Solvent | Water | HCID 962 | — |
| Product | 2,3-Dichloro-4-(p-nitrophenylsulfenyl)anisole | HCID 13145682 | — |
Reaction Steps
A mixture of 2,3-dichloro-4-methoxybenzenethiol (6.0 g., 0.024 mole), p-fluoronitrobenzene (3.04 ml., 0.029 mole) and anhydrous potassium carbonate (5.15 g., 0.038 mole) in 60 ml. of DMF was stirred at room temperature for 2 hours and then poured into water. The resulting solid product was filtered and washed well with ethanol to give 9.1 g. (96%), m.p. 236°-237°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04389416 |
| Source dataset | uspto-grants-1983_06 |
| ORD ID | ord-8f41d96605b049c698fc4f7ffce2e032 |
| Source note | uspto-grants-1983_06 |