Sodium → Alpha-Ionone

HRID 2166904Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 2166904
[Na].O=[C:3]1[CH2:8][C:7]([CH3:10])([CH3:9])[CH:6]([CH2:11][CH2:12]O)[C:5]([CH3:14])=[CH:4]1.CC12[O:24][CH2:23][CH2:22]C1C(C)(C)CC=C2.CC12OCCC1C(C)(C)CC(=O)C2>>[CH3:14][C:5]1[CH:6](/[CH:11]=[CH:12]/[C:23]([CH3:22])=[O:24])[C:7]([CH3:10])([CH3:9])[CH2:8][CH2:3][CH:4]=1

Komponenten

5

Edukt 4

HCID 5360545SodiumHCID 204898632-(4-Keto-2,6,6-trimethylcyclohex-2-en-1-yl)ethanolHCID 204898661,5,5-Trimethyl-9-oxa-bicyclo[4.3.0]non-2-eneHCID 20489867Hexahydro-4,4,7a-trimethyl-6(2H)-benzofuranone

Produkt 1

HCID 5282108Alpha-Ionone

Versuchsvorschrift

Identification has been carried out by mass spectrum as stated above. The composition can be characterized by the presence of compounds 1 [2-(4-hydroxy-2,6,6-trimethylcyclohex-2-en-1-yl)ethanol] and 2 [2-(4-keto-2,6,6-trimethylcyclohex-2-en-1-yl)ethanol] and especially 3 [1,5,5-trimethyl-9-oxa-bicyclo[4.3.0]non-2-ene] and 4 [1,5,5-trimethyl-9-oxa-bicyclo[4.3.0]nonan-3-one]. (See Table A).

Quellen und Nachweise

ORD-Eintrag
ord-2d31cae629dc4dafbcb2f0954097f925
Quelldatensatz
uspto-grants-1983_06
Patentnummer
US04390557

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