1-Bromo-2-nitrobenzene → HCID 87210606, compound

Participants

Reaction Steps

10 g (21.1 mmol) of 9,10-dinaphthylanthracene-2-boronic acid, 10.64 g (52.7 mmol) of bromonitrobenzene, 1.21 g (0.05 mmol) of Pd(PPh3)4, and 11.65 g (84.3 mmol) of K2CO3 were diluted with 100 ml of dioxane, 100 ml of THF, and 30 ml of H2O, and then, the mixture was refluxed while heating. After 12 hours, a solvent was removed and the resultant mixture was extracted using MC and washed with a saturated NaCl solution. Then, an organic layer was dried and condensed over MgSO4, and the obtained product was purified by column chromatography (MC/Hex=1/5), thereby producing 2-(2-nitrophenyl)-9,10-di(2-naphthyl)anthracene that was yellow solid (8.4 g, 73%).

Provenance & Evidence