Ethanol → HCID 58561902, compound

Participants

Reaction Steps

To an ice-cooled solution of sodium 1H-1,2,3-triazole-4-thiolate (30, 1.0 g, 8.13 in EtOH (10 mL) was added benzyl bromide (1.4 g, 8.13 mmol) drop-wise. The mixture stirred at room temperature for 20 minutes then diluted with EtOAc and washed with water (10 mL), brine (10 mL), dried over Na2SO4, filtered and concentrated under reduced pressure to give 4-(benzylthio)-1-methyl-1H-1,2,3-triazole as a white solid (55, 1.5 g, 93%); 1H NMR (300 MHz, CDCl3): δ 13.37 (bs, 1H), 7.48 (s, 1H), 7.21 (m, 5H), 4.09 (s, 2H).

Provenance & Evidence