Furfuryl Alcohol → Furfuryl Alcohol

HRID 2168858Notes

Reaction equation

HRID 2168858 reaction equation
[C:1](=[O:6])([O:4][CH3:5])[O:2][CH3:3].[CH2:7]([OH:13])[C:8]1[O:12][CH:11]=[CH:10][CH:9]=1>>[C:1](=[O:6])([O:4][CH2:5][C:11]1[O:12][CH:8]=[CH:9][CH:10]=1)[O:2][CH2:3][C:11]1[O:12][CH:8]=[CH:9][CH:10]=1.[C:1](=[O:2])([OH:6])[OH:4].[CH2:1]([OH:6])[CH2:10][CH2:9][CH:8]([OH:12])[CH3:7].[CH2:7]([OH:13])[C:8]1[O:12][CH:11]=[CH:10][CH:9]=1

Participants

5

Reactant 2

HCID 7361Furfuryl AlcoholHCID 12021Dimethyl Carbonate

Product 3

HCID 7361Furfuryl AlcoholHCID 86702297HCID 86702297, compoundHCID 867022981,4-Pentanediol carbonate

Procedure

Adding dimethyl carbonate and furfuryl alcohol in a tubular ester exchange reactor; then adding the metal-rare earth oxide composite catalyst prepared by the embodiment 1, mixing uniformly and performing an ester exchange reaction, then distilling the reaction product to obtain difurfuryl carbonate, wherein the mole ratio of 1,4-pentanediol carbonate to furfuryl alcohol is 1:6, and the weight ratio of the metal-rare earth oxide composite catalyst to the total weight of dimethyl carbonate and furfuryl alcohol is 0.5:100; the ester exchange reaction is performed at a temperature of 160° C. and under an absolute pressure of 3 MPa for 20 minutes; in the ester exchange reaction, the conversion rate of dimethyl carbonate is 95%, and yield of difurfuryl carbonate is 90%.

Workup

  1. customprepared by the embodiment 1
  2. additionmixing uniformly
  3. distillationdistilling the reaction product

Sources & evidence

ORD record
ord-07075a46689b49f88be1906f3fece185
Source dataset
uspto-grants-2015_06
Patent number
US09045707B2

Reaction notes

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