Dinitrobenzonitrile → HCID 66746863, compound

HRID 2169989Notes

Reaction equation

[OH:1][CH:2]1[CH2:7][CH2:6][CH2:5][CH2:4][CH:3]1[O:8][C:9]1[CH:10]=[C:11]([CH:18]=[CH:19][C:20]=1[O:21][CH3:22])[C:12]([NH:14][CH:15]([CH3:17])[CH3:16])=[O:13].[N+:23]([C:26]1[CH:33]=[CH:32][CH:31]=[C:30]([N+]([O-])=O)[C:27]=1[C:28]#[N:29])([O-:25])=[O:24]>>[C:28]([C:27]1[C:26]([N+:23]([O-:25])=[O:24])=[CH:33][CH:32]=[CH:31][C:30]=1[O:1][CH:2]1[CH2:7][CH2:6][CH2:5][CH2:4][CH:3]1[O:8][C:9]1[CH:10]=[C:11]([CH:18]=[CH:19][C:20]=1[O:21][CH3:22])[C:12]([NH:14][CH:15]([CH3:16])[CH3:17])=[O:13])#[N:29]

Participants

Reactant 2

HCID 520718Dinitrobenzonitrile

HCID 66747248HCID 66747248, compound

Product 1

HCID 66746863HCID 66746863, compound

Procedure

Prepared as in Example 126c from (±)-3-((2-hydroxycyclohexyl)oxy)-N-isopropyl-4-methoxybenzamide (Example 129d) and 2,6-dinitrobenzonitrile as a brown solid (100%). MS 454 (MH+).

Sources & evidence

ORD record: ord-fea18344d1d74dda87b4fea5f2d28faf
Source dataset: uspto-grants-2015_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US09049878B2

Reaction notes

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