Stearic Acid → Octadecanoic acid, strontium salt (2:1)

HRID 2170010Notes

Reaction equation

HRID 2170010 reaction equation
[C:1]([OH:20])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[OH-].[Na+].O.O.O.O.O.O.[Cl-].[Sr+2:30].[Cl-]>O.C(O)C.O>[C:1]([O-:20])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[Sr+2:30].[C:1]([O-:20])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]

Participants

6

Reactant 3

HCID 5281Stearic AcidHCID 14798Sodium HydroxideHCID 610186810025-70-4

Product 1

HCID 165843Octadecanoic acid, strontium salt (2:1)

Reagents, catalysts & solvents 2

HCID 962WaterSolventHCID 19096565Water ethanolSolvent

Procedure

Stearic acid (2.97 g, 10.4 mmol) was dissolved in water/ethanol (100 ml, 50:50 (volume)) containing sodium hydroxide (0.417 g, 10.4 mmol). The mixture was heated to 70.degree. C. and a solution of strontium chloride hexahydrate (1.39 g, 5.2 mmol) in water (3 ml) was added. The title compound was isolated by centrifugation of the formed precipitate. Yield 1.6 g (46%).

Workup

  1. temperatureThe mixture was heated to 70.degree

Sources & evidence

ORD record
ord-2d54c6029f094b93b4b9ab3386b905db
Source dataset
uspto-grants-2015_06
Patent number
US09050312B2

Reaction notes

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