1-Decene → HCID 86706735, compound

Participants

Reaction Steps

0.1% catalyst loading: p-Tolyl azide (0.240 g, 1.81 mmol), 1-decene (7.410 g, 52.8 mmol), and [(Me,EtTCPh)Fe(NCCH3)2](PF6)2 (0.0025 g, 0.0018 mmol) were used in the General Catalytic Reaction described above yielding 0.312 g, 70.4%. 1% catalyst loading: p-Tolyl azide (0.103 g, 0.773 mmol), 1-decene (2.223 g, 15.8 mmol), and [(Me,EtTCPh)Fe(NCCH3)2](PF6)2 (0.0107 g, 0.0077 mmol) were used in the General Catalytic Reaction described above yielding 0.156 g, 82.1%. 1H NMR (CDCl3, 499.74 MHz): δ 7.03 (d, J=7.5 Hz, 2H), 6.89 (d, J=7.0 Hz, 2H), 2.28 (s, 3H), 2.03 (m, 3H), 1.59 (m, 4H), 1.40 (m, 2H), 1.31 (m, 8H), 0.91 (t, J=6.0 Hz, 3H). 13C NMR (CDCl3, 125.66 MHz): δ 152.77, 131.45, 129.51, 120.65, 40.33, 34.17, 33.41, 32.02, 29.74, 29.69, 29.42, 27.85, 22.80, 20.78, 14.24. GC/MS (m/z): 245.2. DART HR MS (m/z): [M+H]+246.2211 (found). C17H28N, 246.2222 (calcd).

Provenance & Evidence