反应详情

p-Tolyl azide (0.113 g, 0.852 mmol), trans-4-octene (3.705 g, 33.0 mmol), and [(Me,EtTCPh)Fe(NCCH3)2](PF6)2 (0.0118 g, 0.0085 mmol) were used in the General Catalytic Reaction described above yielding 0.055 g, 30%. 1H NMR (CDCl3, 499.74 MHz): δ 7.02 (d, J=7.5 Hz, 2H), 6.80 (d, J=8.5 Hz, 2H), 2.28 (s, 3H), 2.03 (t, J=5.5 Hz, 2H), 1.62 (m, 2H), 1.53 (m, 4H), 1.10 (m, 2H), 0.96 (t, J=7.0 Hz, 6H) 13C NMR (CDCl3, 125.66 MHz): δ 148.10, 130.91, 129.36, 120.95, 44.99, 33.29, 21.11, 20.80, 14.18. GC/MS (m/z): 217.2. DART HR MS (m/z): [M+H]+218.1901 (found). C5H24N, 218.1909 (calcd).

1. customabove yielding 0.055 g, 30%