1-Methylcyclohexene → HCID 86706738, compound

Participants

Reaction Steps

p-Tolyl azide (0.100 g, 0.751 mmol), 1-methyl-cyclohexene (4.055 g, 42.2 mol), and [(Me,EtTCPh)Fe(NCCH3)2](PF6)2 (0.0104 g, 0.0075 mmol) were used in the General Catalytic Reaction described above yielding 0.059 g, 39%. 1H NMR (CDCl3, 499.74 MHz): δ 7.02 (d, J=7.5 Hz, 2H), 6.75 (d, J=6.5 Hz, 2H), 2.28 (s, 3H), 2.15 (m, 1H), 2.02 (m, 1H), 1.99 (m, 2H), 1.64 (m, 1H), 1.55 (m, 2H), 1.35 (m, 1H), 1.25 (m, 1H), 0.99 (s, 3H) 13C NMR (CDCl3, 125.66 MHz): δ 148.74, 130.52, 129.27, 120.49, 44.17, 41.60, 32.41, 24.62, 21.16, 20.85, 20.81, 20.65. GC/MS (m/z): 201.1. DART HR MS (m/z): [M+H]+202.1594 (found). C15H22N, 202.1596 (calcd).

Provenance & Evidence