Aziridine → HCID 86706739, compound

Participants

Reaction Steps

Selected control reactions following the method of the General Catalytic Reaction were attempted but without [(Me,EtTCPh)Fe(NCCH3)2](PF6)2. These reactions either gave lower yields for aziridines or almost no isolable aziridine. Two example cases are shown. 2-octyl-1-(ptolyl)aziridine. p-Tolyl azide (0.096 g, 0.72 mmol) and 1-decene (1.853 g, 13.2 mmol) were used in the General Catalytic Reaction described above yielding 0.078 g, 43% yield. 1-methyl-7-(p-tolyl)-7-azabicyclo[4.1.0]heptane. p-Tolyl azide (0.203 g, 1.53 mmol) and 1-methylcyclohexene (4.055 g, 42.2 mol) were used in the General Catalytic Reaction described above yielding 0.007 g, 2% yield.

Provenance & Evidence