Sesamol → 2-(3,4-methylenedioxy-phenoxy)-2-methylthio-N-(2-methylpent-3-yn-2-yl)acetamide

HRID 217156Notes

Reaction equation

[CH2:1]1[O:9][C:8]2[CH:7]=[CH:6][C:5]([OH:10])=[CH:4][C:3]=2[O:2]1.Cl[CH:12]([S:22][CH3:23])[C:13]([NH:15][C:16]([CH3:21])([C:18]#[C:19][CH3:20])[CH3:17])=[O:14]>>[CH2:1]1[O:9][C:8]2[CH:7]=[CH:6][C:5]([O:10][CH:12]([S:22][CH3:23])[C:13]([NH:15][C:16]([CH3:17])([C:18]#[C:19][CH3:20])[CH3:21])=[O:14])=[CH:4][C:3]=2[O:2]1

Participants

Reactant 2

HCID 68289Sesamol

HCID 866108822-chloro-2-methylthio-N-(2-methylpent-3-yn-2-yl)acetamide

Product 1

HCID 688046212-(3,4-methylenedioxy-phenoxy)-2-methylthio-N-(2-methylpent-3-yn-2-yl)acetamide

Procedure

In a similar procedure, 3,4-methylenedioxyphenol was reacted with 2-(chloro)-2-(methylthio)-N-(2-methylpent-3-yn-2-yl)acetamide to give 2-(3,4-methylenedioxy-phenoxy)-2-methylthio-N-(2-methylpent-3-yn-2-yl)acetamide (Compound No. 4 of Table 3).

Sources & evidence

ORD record: ord-078f631621f443ec8bce774b0dd9076b
Source dataset: uspto-grants-2012_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08193361B2

Reaction notes

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