HCID 86701521, compound → HCID 178489068, compound

Participants

Reaction Steps

The title compound was synthesized from a mixture of (±)-tert-butyl 4-((5-cyano-1-((2-(trimethylsilyl)ethoxy)methyl)-1H-benzo[d]imidazol-2-yl)(1,1-dimethylethylsulfinamido)methyl)-5-methoxy-7-methyl-1H-indole-1-carboxylate and (±)-tert-butyl 4-((6-cyano-1-((2-(trimethylsilyl)ethoxy)methyl)-1H-benzo[d]imidazol-2-yl)(1,1-dimethylethylsulfinamido)methyl)-5-methoxy-7-methyl-1H-indole-1-carboxylate following the same procedure as described in Example 36-E. 1H NMR (400 MHz, DMSO-d6) δ ppm 10.91 (br. s., 1H) 7.91 (s, 1H) 7.57 (d, J=8.08 Hz, 1H) 7.47 (dd, J=8.34, 1.52 Hz, 1H) 7.19 (t, J=2.78 Hz, 1H) 6.74 (s, 1H) 6.23 (dd, J=3.03, 2.02 Hz, 1H) 5.80 (s, 1H) 3.71 (s, 3H) 2.44 (s, 3H). HRMS calcd. for C19H17N5O (M+H)+ 332.1506. found 332.1507.

Provenance & Evidence