Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Nitrogen | HCID 947 | — |
| Reactant | Stannane, tributyl(1-ethoxyethenyl)- | HCID 619414 | — |
| Reactant | HCID 86696275 | HCID 86696275 | — |
| Catalyst | HCID 178418476 | HCID 178418476 | — |
| Solvent | 1,4-Dioxane | HCID 31275 | — |
| Product | HCID 86696274 | HCID 86696274 | — |
Reaction Steps
The solution of (77.1) (110 mg, 0.249 mmol) and PdCl2(PPh3)2 (17.45 mg, 0.025 mmol) in 1,4-dioxane (4 ml) was bubbled by N2 for 5 min. Tributyl(1-ethoxyvinyl)stannane (135 mg, 0.373 mmol) was added. The reaction tube was flushed by N2 for 5 min again and sealed. The sealed-tube was stirred at 120° C. for 2 h. The reaction was evaporated to dryness and the residue was directly used in the next step. LCMS (method A): [M+H]+=433.6, tR=2.54 min.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US09062045B2 |
|---|
| Source dataset | uspto-grants-2015_06 |
|---|
| ORD ID | ord-00208f1eec2c47d195bc1b8a17e1cf98 |
|---|
| Source note | uspto-grants-2015_06 |
|---|
