HCID 131732985, compound → HCID 68264829, compound

Participants

Reaction Steps

3.98 g of the 2,3,4,6-tetra-O-acetyl-1-{4-chloro-3-[1-(4-ethyoxyphenyl)-1-fluoroethyl]phenyl}-1-deoxy-β-D-glucopyranose prepared as above was dissolved in 7 ml of anhydrous methanol containing 0.11 g of sodium methoxide, and stirred for 5 hours at room temperature, and then 1 g of dried strongly acidic resin was added, and stirred overnight at room temperature. The resin was removed by filtration, and the resulting filtrate was evaporated to dryness on a rotary evaporator to afford a white solid, which was 1-{4-chloro-3-[(4-ethyoxyphenyl)-1-fluoroethyl]phenyl}-1-deoxy-β-D-glucopyranose. ESI-MS, m/z=441.2 ([M+1]).

Provenance & Evidence