HuagongsheHuagongshe Chemistry Print Report · For research reference only
Carbon Tetrachloride → HCID 57696849, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Carbon Tetrachloride | HCID 5943 | — |
| Reactant | Triphenylphosphine | HCID 11776 | — |
| Reactant | HCID 57696848 | HCID 57696848 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Product | HCID 57696849 | HCID 57696849 | 87.3% |
Reaction Steps
A mixture of 8 (82 mg, 0.2 mmol), Ph3P (85 mg, 3.32 mmol), CCl4 (54 mg, 0.35 mmol, dried with CaCl2), and CH3CN (2 mL, dried with CaH2) was stirred for 30 min under argon. The mixture was flash chromatographed (SiO2, 2.5×5 cm. 5% EtOAc-hexanes) to give 9 (70 mg, 77%). This unstable compound was immediately used in the next step.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08198263B2 |
| Source dataset | uspto-grants-2012_06 |
| ORD ID | ord-001493204e2741b1b9003aa23b135c4b |
| Source note | uspto-grants-2012_06 |