1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-6-iodohexane → HCID 102598921, compound

Participants

Reaction Steps

Under a nitrogen atmosphere, 9,10-dibromoanthracene (0.6 g, 1.78 mmol) and a copper powder (1.14 g, 17.8 mmol) were added to a 200 mL reaction vessel and were dissolved in anhydrous dimethyl sulfoxide (25 mL). α,α,α-Benzotrifluoride (25 mL) and C6F13I (1.96 mL, 8.93 mmol) were added thereto and reaction was carried out at 130° C. for 4 hours. After quenching with ice-water, the reaction solution was extracted with methylene chloride. Thereafter, the obtained organic layer was dried over anhydrous sodium sulfate and then filtrated. The filtrate was subjected to solvent removal on a rotary evaporator and, thereafter, separation and purification were conducted by using column chromatography. A 9,10-bis(perfluorohexyl)anthracene was obtained as a yellow solid.

Provenance & Evidence