3-methyl-5-(2,6,6-trimethylcyclohex-1-en-1-yl)pent-1-yn-3-ol → HCID 71761674, compound

Participants

Reaction Conditions

Reaction Steps

Under nitrogen atmosphere, 16.1 mg (0.03 mmol, 5 mol-%) of [(C5(CH3)5)RuCl(μ2-SMe)2Ru(C5(CH3)5)Cl] were dissolved in 7.5 ml of anhydrous 1,2-dichloroethane. To the dark red solution was added drop wise at room temperature a solution of 129 mg (0.5 mmol) of 3-methyl-5-(2,6,6-trimethylcyclohex-1-enyl)pent-1-yn-3-ol (compound of formula (II)) in 5.0 ml of anhydrous 1,2-dichloroethane. After complete addition of the starting material, the solution was heated to 60° C. After 24 hours at 60° C. the brown solution was cooled to room temperature.

Provenance & Evidence