N,N-dimethyl-m-phenylenediamine → HCID 68487291, compound

HRID 2176958Notes

Reaction equation

HRID 2176958 reaction equation
Br[C:2]1[CH:3]=[C:4]([N:8]([CH2:19][CH2:20][O:21][Si:22]([C:25]([CH3:28])([CH3:27])[CH3:26])([CH3:24])[CH3:23])[CH2:9][CH2:10][O:11][Si:12]([C:15]([CH3:18])([CH3:17])[CH3:16])([CH3:14])[CH3:13])[CH:5]=[CH:6][CH:7]=1.[CH3:29][N:30]([CH3:38])[C:31]1[CH:36]=[CH:35][CH:34]=[C:33]([NH2:37])[CH:32]=1>>[CH3:29][N:30]([CH3:38])[C:31]1[CH:32]=[C:33]([NH:37][C:2]2[CH:3]=[C:4]([N:8]([CH2:19][CH2:20][O:21][Si:22]([C:25]([CH3:28])([CH3:27])[CH3:26])([CH3:24])[CH3:23])[CH2:9][CH2:10][O:11][Si:12]([C:15]([CH3:18])([CH3:17])[CH3:16])([CH3:14])[CH3:13])[CH:5]=[CH:6][CH:7]=2)[CH:34]=[CH:35][CH:36]=1

Participants

3

Reactant 2

HCID 76084N,N-dimethyl-m-phenylenediamineHCID 68481968HCID 68481968, compound

Product 1

HCID 68487291HCID 68487291, compound

Procedure

By proceeding as described in the coupling general procedure, but starting from 1.85 g (3.8 mmol) of (3-bromo-phenyl)-bis-[2-(tert-butyldimethylsilanyloxy)ethyl]amine and 1.15 g (4.42 mmol) of N,N-dimethylbenzene-1,3-diamine, [3-(3-dimethylaminophenylamino)phenyl]-bis-[2-(tert-butyldimethylsilanyloxy)ethyl]amine is obtained as a pale yellow oil.

Sources & evidence

ORD record
ord-746719e3740e4722bb20b6484d927cbb
Source dataset
uspto-grants-2015_06
Patent number
US09067900B2

Reaction notes

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