Methyl 3-bromo-6-bromomethyl-2-methoxybenzoate → Methyl 3-bromo-6-bromomethyl-2-hydroxybenzoate

HRID 2177726Notes

Reaction equation

HRID 2177726 reaction equation
C1(S(CC2C(C(OCC)=O)=C(O)C(Br)=CC=2)(=O)=O)C=CC=CC=1.[Br:24][C:25]1[C:26]([O:37]C)=[C:27]([C:32]([CH2:35][Br:36])=[CH:33][CH:34]=1)[C:28]([O:30][CH3:31])=[O:29]>>[Br:24][C:25]1[C:26]([OH:37])=[C:27]([C:32]([CH2:35][Br:36])=[CH:33][CH:34]=1)[C:28]([O:30][CH3:31])=[O:29]

Participants

3

Reactant 2

HCID 66685947Methyl 3-bromo-6-bromomethyl-2-methoxybenzoate2×HCID 67108192Ethyl 6-(benzenesulphonylmethyl)-3-bromo-2-hydroxybenzoate

Product 1

HCID 67107930Methyl 3-bromo-6-bromomethyl-2-hydroxybenzoate

Procedure

Prepared by proceeding in a similar manner to Intermediate 52, starting from methyl 3-bromo-6-bromomethyl-2-methoxybenzoate (Intermediate 89).

Workup

  1. customPrepared

Sources & evidence

ORD record
ord-55a418cbf8a54130b7dd41576c2ca9b2
Source dataset
uspto-grants-2015_06
Patent number
US09067905B2

Reaction notes

Loading…