Ethyl 6-(benzenesulphonylmethyl)-3-bromo-2-methoxybenzoate → Methyl 6-(benzenesulfonylmethyl)-3-bromo-2-methoxybenzoate

HRID 2177736Notes

Reaction equation

HRID 2177736 reaction equation
[C:1]1([S:7]([CH2:10][C:11]2[C:16]([C:17]([O:19][CH2:20]C)=[O:18])=[C:15]([O:22][CH3:23])[C:14]([Br:24])=[CH:13][CH:12]=2)(=[O:9])=[O:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.BrC1C(OC)=C(C(CSC2C=CC=CC=2)=CC=1)C(OC)=O>>[C:1]1([S:7]([CH2:10][C:11]2[C:16]([C:17]([O:19][CH3:20])=[O:18])=[C:15]([O:22][CH3:23])[C:14]([Br:24])=[CH:13][CH:12]=2)(=[O:9])=[O:8])[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

Participants

3

Procedure

Prepared by proceeding in a similar manner to Intermediate 61, starting from methyl 3-bromo-6-(phenylthiomethyl)-2-methoxybenzoate (Intermediate 80).

Workup

  1. customPrepared

Sources & evidence

ORD record
ord-aba22331a38b4125876d2c28626d3e36
Source dataset
uspto-grants-2015_06
Patent number
US09067905B2

Reaction notes

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