Ethyl 6-(benzenesulphonylmethyl)-3-bromo-2-methoxybenzoate → Methyl 3-bromo-6-(2-bromobenzenesulphonylmethyl)-2-methoxybenzoate

HRID 2177737Notes

Reaction equation

HRID 2177737 reaction equation
[C:1]1([S:7]([CH2:10][C:11]2[C:16]([C:17]([O:19][CH2:20]C)=[O:18])=[C:15]([O:22][CH3:23])[C:14]([Br:24])=[CH:13][CH:12]=2)(=[O:9])=[O:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Br:25]C1C(OC)=C(C(CSC2C=CC=CC=2Br)=CC=1)C(OC)=O>>[Br:24][C:14]1[C:15]([O:22][CH3:23])=[C:16]([C:11]([CH2:10][S:7]([C:1]2[CH:6]=[CH:5][CH:4]=[CH:3][C:2]=2[Br:25])(=[O:9])=[O:8])=[CH:12][CH:13]=1)[C:17]([O:19][CH3:20])=[O:18]

Participants

3

Reactant 2

HCID 67107394Ethyl 6-(benzenesulphonylmethyl)-3-bromo-2-methoxybenzoateHCID 67107621Methyl 3-bromo-6-(2-bromophenylthiomethyl)-2-methoxybenzoate2×

Product 1

HCID 67107593Methyl 3-bromo-6-(2-bromobenzenesulphonylmethyl)-2-methoxybenzoate

Procedure

Prepared by proceeding in a similar manner to Intermediate 61, starting from methyl 3-bromo-6-(2-bromophenylthiomethyl)-2-methoxybenzoate (Intermediate 81).

Workup

  1. customPrepared

Sources & evidence

ORD record
ord-8ce8c9a1bb7b4bdf8a1eeca08be6e390
Source dataset
uspto-grants-2015_06
Patent number
US09067905B2

Reaction notes

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