Thioguaiacol → HCID 67107546, compound

HRID 2177743Notes

Reaction equation

HRID 2177743 reaction equation
[Br:1][C:2]1[C:3]([O:21][CH3:22])=[C:4]([C:10]([CH2:13][S:14][C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)=[CH:11][CH:12]=1)[C:5]([O:7][CH2:8]C)=[O:6].BrC1C(OC)=C(C(CBr)=CC=1)[C:27](OC)=[O:28].COC1C=CC=CC=1S>>[Br:1][C:2]1[C:3]([O:21][CH3:22])=[C:4]([C:10]([CH2:13][S:14][C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][C:16]=2[O:28][CH3:27])=[CH:11][CH:12]=1)[C:5]([O:7][CH3:8])=[O:6]

Participants

4

Reactant 3

HCID 23642ThioguaiacolHCID 66685947Methyl 3-bromo-6-bromomethyl-2-methoxybenzoate2×HCID 67107500HCID 67107500, compound

Product 1

HCID 67107546HCID 67107546, compound

Procedure

Prepared by proceeding in a similar manner to Intermediate 73, starting from methyl 3-bromo-6-bromomethyl-2-methoxybenzoate (Intermediate 89) and 2-methoxythiophenol.

Workup

  1. customPrepared

Sources & evidence

ORD record
ord-744cf19d88964f20acb4ebb932b0ffa4
Source dataset
uspto-grants-2015_06
Patent number
US09067905B2

Reaction notes

Loading…