3-Chlorothiophenol → HCID 67107689, compound

HRID 2177746Notes

Reaction equation

HRID 2177746 reaction equation
BrC1C(OC)=C(C=CC=1CSC1C=CC=CC=1C)C(OCC)=O.[Br:24][C:25]1[C:26]([O:44][CH3:45])=[C:27]([C:33]([CH2:36][S:37][C:38]2[CH:43]=[CH:42][CH:41]=[CH:40][CH:39]=2)=[CH:34][CH:35]=1)[C:28]([O:30][CH2:31][CH3:32])=[O:29].[Cl:46]C1C=C(S)C=CC=1>>[Br:24][C:25]1[C:26]([O:44][CH3:45])=[C:27]([C:33]([CH2:36][S:37][C:38]2[CH:43]=[CH:42][CH:41]=[C:40]([Cl:46])[CH:39]=2)=[CH:34][CH:35]=1)[C:28]([O:30][CH2:31][CH3:32])=[O:29]

Participants

4

Reactant 3

HCID 162573-ChlorothiophenolHCID 67107500HCID 67107500, compound2×HCID 67107587Ethyl 3-bromo-2-methoxy-(2-methylphenylthiomethyl)benzoate

Product 1

HCID 67107689HCID 67107689, compound

Procedure

Prepared by proceeding in a similar manner to Intermediate 77, starting from ethyl 3-bromo-6-bromomethyl-2-methoxybenzoate (Intermediate 87) and 3-chlorothiophenol.

Workup

  1. customPrepared

Sources & evidence

ORD record
ord-1adf9c0e73ee43fabe11ffbc7093b714
Source dataset
uspto-grants-2015_06
Patent number
US09067905B2

Reaction notes

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