Methyl 3-bromo-2-methoxy-6-(3-methoxyphenylthiomethyl)benzoate → Methyl 3-bromo-2-methoxy-6-(3-methoxybenzenesulphonylmethyl)benzoate

HRID 2177764Notes

Reaction equation

HRID 2177764 reaction equation
[Br:1][C:2]1[C:3]([O:23][CH3:24])=[C:4]([C:9]([CH2:12][S:13]([C:16]2[CH:21]=[CH:20][CH:19]=[C:18](Cl)[CH:17]=2)(=[O:15])=[O:14])=[CH:10][CH:11]=1)[C:5]([O:7][CH3:8])=[O:6].BrC1C(OC)=C(C(CSC2C=CC=C(OC)C=2)=CC=1)[C:29](OC)=[O:30]>>[Br:1][C:2]1[C:3]([O:23][CH3:24])=[C:4]([C:9]([CH2:12][S:13]([C:16]2[CH:21]=[CH:20][CH:19]=[C:18]([O:30][CH3:29])[CH:17]=2)(=[O:15])=[O:14])=[CH:10][CH:11]=1)[C:5]([O:7][CH3:8])=[O:6]

Participants

3

Reactant 2

HCID 67107527Methyl 3-bromo-2-methoxy-6-(3-methoxyphenylthiomethyl)benzoate2×HCID 67107903Methyl 3-bromo-6-(3-chlorobenzenesulphonylmethyl)-2-methoxybenzoate

Product 1

HCID 67107955Methyl 3-bromo-2-methoxy-6-(3-methoxybenzenesulphonylmethyl)benzoate

Procedure

Prepared by proceeding in a similar manner to Intermediate 68, starting from methyl 3-bromo-2-methoxy-6-(3-methoxyphenylthiomethyl)benzoate (Intermediate 105).

Workup

  1. customPrepared

Sources & evidence

ORD record
ord-b29782ec59c842afb1619243de080cb9
Source dataset
uspto-grants-2015_06
Patent number
US09067905B2

Reaction notes

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