3-Methoxybenzenethiol → Methyl 3-bromo-2-methoxy-6-(3-methoxyphenylthiomethyl)benzoate

HRID 2177768Notes

Reaction equation

HRID 2177768 reaction equation
[Br:1][C:2]1[C:3]([O:21][CH3:22])=[C:4]([C:10]([CH2:13][S:14][C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)=[CH:11][CH:12]=1)[C:5]([O:7][CH2:8]C)=[O:6].BrC1C(OC)=C(C(CBr)=CC=1)[C:27](OC)=[O:28].COC1C=C(S)C=CC=1>>[Br:1][C:2]1[C:3]([O:21][CH3:22])=[C:4]([C:10]([CH2:13][S:14][C:15]2[CH:20]=[CH:19][CH:18]=[C:17]([O:28][CH3:27])[CH:16]=2)=[CH:11][CH:12]=1)[C:5]([O:7][CH3:8])=[O:6]

Participants

4

Reactant 3

HCID 849893-MethoxybenzenethiolHCID 66685947Methyl 3-bromo-6-bromomethyl-2-methoxybenzoate2×HCID 67107500HCID 67107500, compound

Product 1

HCID 67107527Methyl 3-bromo-2-methoxy-6-(3-methoxyphenylthiomethyl)benzoate

Procedure

Prepared by proceeding in a similar manner to Intermediate 73, starting from methyl 3-bromo-6-bromomethyl-2-methoxybenzoate (Intermediate 89) and 3-methoxythiophenol.

Workup

  1. customPrepared

Sources & evidence

ORD record
ord-adee3e3ab5554938a23d44f5cfdd2ce7
Source dataset
uspto-grants-2015_06
Patent number
US09067905B2

Reaction notes

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