Methyl 3-bromo-6-(3-chlorobenzenesulphonylmethyl)-2-hydroxybenzoate → Methyl 6-(benzenesulphonylmethyl)-3-ethyl-2-hydroxybenzoate

HRID 2177773Notes

Reaction equation

HRID 2177773 reaction equation
BrC1C(O)=C(C(CS(C2C=CC=C(Cl)C=2)(=O)=O)=CC=1)C(OC)=O.[C:24]1([S:30]([CH2:33][C:34]2[C:39]([C:40]([O:42][CH3:43])=[O:41])=[C:38]([O:44]C)[C:37]([CH2:46][CH3:47])=[CH:36][CH:35]=2)(=[O:32])=[O:31])[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1>>[C:24]1([S:30]([CH2:33][C:34]2[C:39]([C:40]([O:42][CH3:43])=[O:41])=[C:38]([OH:44])[C:37]([CH2:46][CH3:47])=[CH:36][CH:35]=2)(=[O:32])=[O:31])[CH:25]=[CH:26][CH:27]=[CH:28][CH:29]=1

Participants

3

Reactant 2

HCID 67107545Methyl 3-bromo-6-(3-chlorobenzenesulphonylmethyl)-2-hydroxybenzoateHCID 67107654Methyl 6-(benzenesulphonylmethyl)-3-ethyl-2-methoxybenzoate2×

Product 1

HCID 67107635Methyl 6-(benzenesulphonylmethyl)-3-ethyl-2-hydroxybenzoate

Procedure

Prepared by proceeding in a similar manner to Intermediate 54, starting from methyl 6-(benzenesulphonylmethyl)-3-ethyl-2-methoxybenzoate (Intermediate 111).

Workup

  1. customPrepared

Sources & evidence

ORD record
ord-994adf59775f477696b8c7b105245ea0
Source dataset
uspto-grants-2015_06
Patent number
US09067905B2

Reaction notes

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