t-Butyl 6-(benzenesulphinylmethyl)-3-(furan-3-yl)-2-methoxybenzoate → t-butyl 3-(furan-3-yl)-2-methoxy-6-{[S-phenyl-N-(trifluoroacetyl)sulphonimidoyl]methyl}benzoate

HRID 2177860Notes

Reaction equation

HRID 2177860 reaction equation
O1C=CC(C2C(OC)=C(C(CS(C3C=CC=CC=3)(=[N:19][C:20](=[O:25])[C:21]([F:24])([F:23])[F:22])=O)=CC=2)C(OC)=O)=C1.[C:34]1([S:40]([CH2:42][C:43]2[C:48]([C:49]([O:51][C:52]([CH3:55])([CH3:54])[CH3:53])=[O:50])=[C:47]([O:56][CH3:57])[C:46]([C:58]3[CH:62]=[CH:61][O:60][CH:59]=3)=[CH:45][CH:44]=2)=[O:41])[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=1>>[O:60]1[CH:61]=[CH:62][C:58]([C:46]2[C:47]([O:56][CH3:57])=[C:48]([C:43]([CH2:42][S:40]([C:34]3[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=3)(=[N:19][C:20](=[O:25])[C:21]([F:24])([F:23])[F:22])=[O:41])=[CH:44][CH:45]=2)[C:49]([O:51][C:52]([CH3:55])([CH3:54])[CH3:53])=[O:50])=[CH:59]1

Participants

3

Reactant 2

HCID 67108004t-Butyl 6-(benzenesulphinylmethyl)-3-(furan-3-yl)-2-methoxybenzoate2×HCID 86677125methyl 3-(furan-3-yl)-2-methoxy-6-{[S-phenyl-N-(trifluoroacetyl)sulphonimidoyl]methyl)benzoate

Product 1

HCID 86677128t-butyl 3-(furan-3-yl)-2-methoxy-6-{[S-phenyl-N-(trifluoroacetyl)sulphonimidoyl]methyl}benzoate

Procedure

Prepared by proceeding in a similar manner to Intermediate 215, starting from t-butyl 6-(benzenesulphinylmethyl)-3-(furan-3-yl)-2-methoxybenzoate (Intermediate 221).

Workup

  1. customPrepared

Sources & evidence

ORD record
ord-0be5bb3f87794de9aaf6514c299a84be
Source dataset
uspto-grants-2015_06
Patent number
US09067905B2

Reaction notes

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