Ethyl 6-(benzenesulphinylmethyl)-3-ethyl-2-methoxybenzoate → t-Butyl 6-(benzenesulphinylmethyl)-3-(furan-3-yl)-2-methoxybenzoate

HRID 2177861Notes

Reaction equation

HRID 2177861 reaction equation
C1(S(CC2C(C(OCC)=O)=C(OC)C(CC)=CC=2)=[O:8])C=CC=CC=1.[O:25]1[CH:29]=[CH:28][C:27]([C:30]2[C:31]([O:51][CH3:52])=[C:32]([C:40]([CH2:43][S:44][C:45]3[CH:50]=[CH:49][CH:48]=[CH:47][CH:46]=3)=[CH:41][CH:42]=2)[C:33]([O:35][C:36]([CH3:39])([CH3:38])[CH3:37])=[O:34])=[CH:26]1>>[C:45]1([S:44]([CH2:43][C:40]2[C:32]([C:33]([O:35][C:36]([CH3:39])([CH3:38])[CH3:37])=[O:34])=[C:31]([O:51][CH3:52])[C:30]([C:27]3[CH:28]=[CH:29][O:25][CH:26]=3)=[CH:42][CH:41]=2)=[O:8])[CH:50]=[CH:49][CH:48]=[CH:47][CH:46]=1

Participants

3

Reactant 2

HCID 67107367Ethyl 6-(benzenesulphinylmethyl)-3-ethyl-2-methoxybenzoateHCID 67107958t-Butyl 3-(furan-3-yl)-2-methoxy-6-(phenylthiomethyl)benzoate2×

Product 1

HCID 67108004t-Butyl 6-(benzenesulphinylmethyl)-3-(furan-3-yl)-2-methoxybenzoate

Procedure

Prepared by proceeding in a similar manner to Intermediate 2, starting from t-butyl 3-(furan-3-yl)-2-methoxy-6-(phenylthiomethyl)benzoate (Intermediate 222).

Workup

  1. customPrepared

Sources & evidence

ORD record
ord-676c139acd214b76b4c70cc390d7d58b
Source dataset
uspto-grants-2015_06
Patent number
US09067905B2

Reaction notes

Loading…