Ethyl 6-(benzenesulphinylmethyl)-3-ethyl-2-methoxybenzoate → Benzyl 6-[(N-cyano-S-phenylsulphonimidoyl)methyl]-3-(furan-3-yl)-2-methoxybenzoate

HRID 2177863Notes

Reaction equation

HRID 2177863 reaction equation
C1(S(CC2C(C(OCC)=O)=C(OC)C(CC)=CC=2)=[O:8])C=CC=CC=1.[C:25]([N:27]=[S:28]([CH2:35][C:36]1[C:41]([C:42]([O:44][CH2:45][C:46]2[CH:51]=[CH:50][CH:49]=[CH:48][CH:47]=2)=[O:43])=[C:40]([O:52][CH3:53])[C:39]([C:54]2[CH:58]=[CH:57][O:56][CH:55]=2)=[CH:38][CH:37]=1)[C:29]1[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=1)#[N:26]>>[C:25]([N:27]=[S:28]([CH2:35][C:36]1[C:41]([C:42]([O:44][CH2:45][C:46]2[CH:47]=[CH:48][CH:49]=[CH:50][CH:51]=2)=[O:43])=[C:40]([O:52][CH3:53])[C:39]([C:54]2[CH:58]=[CH:57][O:56][CH:55]=2)=[CH:38][CH:37]=1)([C:29]1[CH:30]=[CH:31][CH:32]=[CH:33][CH:34]=1)=[O:8])#[N:26]

Participants

3

Reactant 2

HCID 67107367Ethyl 6-(benzenesulphinylmethyl)-3-ethyl-2-methoxybenzoateHCID 86677130benzyl 6-[(N-cyano-S-phenylsulphinimidoyl)methyl]-3-(furan-3-yl)-2-methoxybenzoate2×

Product 1

HCID 86677129Benzyl 6-[(N-cyano-S-phenylsulphonimidoyl)methyl]-3-(furan-3-yl)-2-methoxybenzoate

Procedure

Prepared by proceeding in a similar manner to Intermediate 2, starting from benzyl 6-[(N-cyano-S-phenylsulphinimidoyl)methyl]-3-(furan-3-yl)-2-methoxybenzoate (Intermediate 225).

Workup

  1. customPrepared

Sources & evidence

ORD record
ord-6527e0fe631642e495a99c0929901b01
Source dataset
uspto-grants-2015_06
Patent number
US09067905B2

Reaction notes

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