HuagongsheHuagongshe Chemistry Print Report · For research reference only
[1.1.1]Propellane → HCID 68380148, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | [1.1.1]Propellane | HCID 142022 | — |
| Reactant | HCID 178489560 | HCID 178489560 | — |
| Product | HCID 68380148 | HCID 68380148 | — |
Reaction Steps
Reaction of 2-methoxyphenylmagnesium bromide with [1.1.1]propellane (see A. B. Shtarev et al., J. Am. Chem. Soc. 2001, 123, 3484-3492) afforded 1-(2-methoxyphenyl)bicyclo[1.1.1]pentane, which was treated with boron tribromide to provide the requisite phenol.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09067934B2 |
| Source dataset | uspto-grants-2015_06 |
| ORD ID | ord-5d2b47cb286e4479b1cb68c0d551cf8f |
| Source note | uspto-grants-2015_06 |