HuagongsheHuagongshe Chemistry Print Report · For research reference only
Peracetic Acid → HCID 68380354, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Peracetic Acid | HCID 6585 | — |
| Reactant | (Diethylamino)sulfur trifluoride | HCID 123472 | — |
| Reactant | Bis(pinacolato)diborane | HCID 2733548 | — |
| Reactant | 846032-40-4 | HCID 21073392 | — |
| Reactant | 4-Bromo-1,3-dihydro-2H-inden-2-one | HCID 21073393 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Product | HCID 68380354 | HCID 68380354 | — |
Reaction Steps
4-Bromo-1,3-dihydro-2H-inden-2-one was converted to 4-bromo-2,2-difluoroindane with (diethylamino)sulfur trifluoride. Palladium-catalyzed reaction with bis(pinacolato)diboron, followed by oxidation with peracetic acid, afforded 2,2-difluoroindan-4-ol.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09067934B2 |
| Source dataset | uspto-grants-2015_06 |
| ORD ID | ord-b78252deb9194b4e8c9c4da969809069 |
| Source note | uspto-grants-2015_06 |