Titanium tetrabutoxide → Ethyl(2-hydroxyethyl)phosphinic acid titanium salt

HRID 2179553Notes

Reaction equation

HRID 2179553 reaction equation
[CH2:1]([P:3]([CH2:6][CH2:7][OH:8])(=[O:5])[OH:4])[CH3:2].[O-]CCCC.[O-]CCCC.[O-]CCCC.[O-]CCCC.[Ti+4:29]>C1(C)C=CC=CC=1>[Ti+4:29].[CH2:1]([P:3]([CH2:6][CH2:7][OH:8])(=[O:4])[O-:5])[CH3:2].[CH2:1]([P:3]([CH2:6][CH2:7][OH:8])(=[O:4])[O-:5])[CH3:2].[CH2:1]([P:3]([CH2:6][CH2:7][OH:8])(=[O:4])[O-:5])[CH3:2].[CH2:1]([P:3]([CH2:6][CH2:7][OH:8])(=[O:4])[O-:5])[CH3:2]

Participants

4

Reactant 2

HCID 21801Titanium tetrabutoxideHCID 46832563HCID 46832563, compound

Product 1

HCID 131732617Ethyl(2-hydroxyethyl)phosphinic acid titanium saltYield 91.3%

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

138 g (1 mol) of ethyl(2-hydroxyethyl)phosphinic acid (produced as in Example 9) and 85 g of titanium tetrabutoxide are refluxed in 500 ml of toluene for 40 hours. The resulting butanol is distilled off from time to time with proportions of toluene. The solution formed is subsequently freed of solvent to leave 136 g (91% of theory) of ethyl(2-hydroxyethyl)phosphinic acid titanium salt.

Workup

  1. distillationThe resulting butanol is distilled off from time to time with proportions of toluene
  2. customThe solution formed

Sources & evidence

ORD record
ord-1380aedfda7a4935b4455032ee54342f
Source dataset
uspto-grants-2015_06
Patent number
US09068119B2

Reaction notes

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