Pyridinium chloride → HCID 86701364, compound

Participants

Reaction Conditions

Reaction Steps

Under the nitrogen atmosphere, 9-(7-methoxynaphthalen-2-yl)-10-(4-phenylnaphthalen-1-yl)anthracene (16.0 g) as the twentieth intermediate compound, pyridine hydrochloride (17.3 g) and N-methylpyrrolidone (30 ml) were added to a flask and stirred for 8 hours at 200° C. Once the heating is completed, the mixture was cooled to 100° C. or lower. Liquid separation was performed by adding water and toluene. The solvent was distilled off under reduced pressure and the resulting solid was purified by silica gel column chromatography (solvent: toluene) to give 7-(10-(4-phenylnaphthalen-1-yl)anthracen-9-yl)naphthalen-2-ol (15.5 g) as a twenty-first intermediate compound. The scheme is shown in the following “Reaction 33”.

Provenance & Evidence