Water → HCID 178457459, compound

Participants

Reaction Conditions

Reaction Steps

A 1 L 3-necked round bottom flask equipped with a mechanical stirrer, thermocouple, reflux condenser and heating mantle was charged with C4F9SO2NHC3H7 (93.6 g; 0.27 moles; as prepared above), NaOH (13.6 g; 0.35 moles; pellets) and water (90 mL) and heated at 98° C. for 45 minutes. Upon cooling to 76° C., CHPS (67.5 g; 0.34 moles) was added and the temperature was then increased to 100° C. and maintained for 18 hours. Water was then added (250 mL) and a viscous yellow liquid formed in the bottom of the flask. The upper liquid phase was decanted off and discarded leaving a thick yellow liquid, to which water (250 mL) was added. The temperature of the mixture was increased to 50° C., then cooled to 19° C. Upon removal of water a créme colored solid remained, C4F9SO2N(C3H7)CH2CH(OH)CH2SO3Na (111.4 g; 81% yield).

Provenance & Evidence