Benzene, 1,3-diiodo- → HCID 178506545, compound

HRID 2180895Notes

Reaction equation

HRID 2180895 reaction equation
[C-:1]1([C:6]#[C:7][C:8]2[CH:13]=[CH:12][CH:11]=[C:10](C#C[C-]3C=CC=C3)[CH:9]=2)[CH:5]=[CH:4][CH:3]=[CH:2]1.[CH-:21]1[CH:25]=[CH:24][CH:23]=[CH:22]1.[Fe+2:26].[CH-]1C=CC=C1.[Fe+2].C([C-]1C=CC=C1)#C.[CH-]1C=CC=C1.[Fe+2].[I:46]C1C=CC=C(I)C=1>>[C-:1]1([C:6]#[C:7][C:8]2[CH:13]=[CH:12][CH:11]=[C:10]([I:46])[CH:9]=2)[CH:5]=[CH:4][CH:3]=[CH:2]1.[CH-:21]1[CH:25]=[CH:24][CH:23]=[CH:22]1.[Fe+2:26]

Participants

4

Reactant 3

HCID 12270Benzene, 1,3-diiodo-HCID 15188896HCID 15188896, compoundHCID 168011492HCID 168011492, compound

Product 1

HCID 178506545HCID 178506545, compound

Procedure

Example 11 describes the procedure for producing 1,3-bis(ferrocenylethynyl) benzene 516. Ethynylferrocene 500 was reacted with 1,3-diiodobenzene 502 to form 1-(ferrocenylethynyl)-3-iodobenzene 504. Sufficient ethynylferrocene 500 was present such that the second step of the reaction immediately proceeded. 1-(Ferrocenylethynyl)-3-iodobenzene 504 reacted with ethynylferrocene 514 to form 1,3-bis(ferrocenylethynyl) benzene 516. The reaction procedure is shown in FIG. 5.

Sources & evidence

ORD record
ord-3cffe20be6b74f33ab17d61e8f9d835d
Source dataset
uspto-grants-2005_05
Patent number
US06890504B2

Reaction notes

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