Chloride → HCID 178515942, compound

Participants

Reaction Steps

chloride (compound 29). Two equivalents of salicylaldehyde (2.2 g, 18.1 mmol) was mixed with one equivalent of o-phenylenediamine (920 mg, 8.4 mmol) in methanol that resulted in light orange precipitate of salphen ligand (L8). This ligand (500 mg, 1.6 mmol) was complexed with one equivalent of Fe(III) chloride (295 mg, 1.8 mmol) to obtain compound 29 (65% yield). Observed m/z value for compound 29: 370.18 (M+, —Cl). CHN analysis: Calculated (for C20H14N2O2FeCl. 2.5H2O) C: 53.37%, H, 4.26%, N, 6.22%. Observed: C: 53.32%, H, 3.88%, N, 6.00%.

Provenance & Evidence