HuagongsheHuagongshe Chemistry Print Report · For research reference only
Aluminium lithium hydride → 3-(Undec-4z-enyloxy)benzyl alcohol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Aluminium lithium hydride | HCID 21226445 | — |
| Reactant | HCID 57939201 | HCID 57939201 | — |
| Catalyst | Water | HCID 962 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | 3-(Undec-4z-enyloxy)benzyl alcohol | HCID 57939236 | 99.9% |
Reaction Steps
35 mg of lithium aluminum hydride (922 μmol) are added, at 0° C., to 140 mg of 15 (460 μmol) in ether (3 mL). After reaction for 1 hour 30 minutes, the reaction medium is diluted with ether and hydrolyzed with two drops of water. After filtering through Celite, drying over Na2SO4 and concentrating, 127 mg of a colorless oil are isolated, i.e. a yield of 99%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08198420B2 |
| Source dataset | uspto-grants-2012_06 |
| ORD ID | ord-b51428403257440f9104af6581c97022 |
| Source note | uspto-grants-2012_06 |