1-Chloro-2-(trifluoromethyl)benzene → HCID 22475126, compound

HRID 2184102Notes

Reaction equation

HRID 2184102 reaction equation
[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[C:8](F)(F)F.[Al+3].[Cl-:13].[Cl-:14].[Cl-].[F:16][C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1>>[F:16][C:17]1[CH:22]=[CH:21][C:20]([C:8]([C:3]2[CH:4]=[CH:5][CH:6]=[CH:7][C:2]=2[Cl:1])([Cl:14])[Cl:13])=[CH:19][CH:18]=1

Participants

4

Reactant 3

HCID 69211-Chloro-2-(trifluoromethyl)benzeneHCID 10008FluorobenzeneHCID 6451240Aluminum(III) Chloride

Product 1

HCID 22475126HCID 22475126, compound

Procedure

From 2-chlorobenzotrifluoride (180 mg, 1 mmol), AlCl3 (400 mg, 3 mmol) and fluorobenzene (96 mg, 1 mmol), light yellow oil (380 mg, 131% crude).

Sources & evidence

ORD record
ord-1b0e3d213c4f4261b719c2eac7e8f180
Source dataset
uspto-grants-2005_05
Patent number
US06900227B2

Reaction notes

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