Toluene → HCID 22475235, compound

HRID 2184103Notes

Reaction equation

HRID 2184103 reaction equation
[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[C:8](F)(F)F.[Al+3].[Cl-:13].[Cl-:14].[Cl-].[C:16]1([CH3:22])[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1>>[CH3:22][C:16]1[CH:21]=[CH:20][C:19]([C:8]([C:3]2[CH:4]=[CH:5][CH:6]=[CH:7][C:2]=2[Cl:1])([Cl:14])[Cl:13])=[CH:18][CH:17]=1

Participants

4

Reactant 3

HCID 1140TolueneHCID 69211-Chloro-2-(trifluoromethyl)benzeneHCID 6451240Aluminum(III) Chloride

Product 1

HCID 22475235HCID 22475235, compound

Procedure

From 2-chlorobenzotrifluoride (180 mg, 1 mmol), AlCl3 (400 mg, 3 mmol) and toluene (92 mg, 1 mmol), light yellow oil (345 mg, 120% crude).

Sources & evidence

ORD record
ord-6bee4a9f14cc41548cd5ab084cd05077
Source dataset
uspto-grants-2005_05
Patent number
US06900227B2

Reaction notes

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