1-Bromohexane → HCID 11732181, compound

HRID 2184317Notes

Reaction equation

HRID 2184317 reaction equation
[Cl:1][C:2]1[CH:14]=[CH:13][C:12]2[C:11]3[C:6](=[CH:7][C:8]([Cl:15])=[CH:9][CH:10]=3)[CH2:5][C:4]=2[CH:3]=1.Br[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22]>>[Cl:1][C:2]1[CH:14]=[CH:13][C:12]2[C:11]3[C:6](=[CH:7][C:8]([Cl:15])=[CH:9][CH:10]=3)[C:5]([CH2:13][CH2:14][CH2:2][CH2:3][CH2:4][CH3:12])([CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[C:4]=2[CH:3]=1

Participants

3

Reactant 2

HCID 81011-BromohexaneHCID 2519872,7-Dichlorofluorene

Product 1

HCID 11732181HCID 11732181, compoundYield 91%

Procedure

2,7-Dichloro-9,9-di(1-hexyl)fluorene is prepared from 2,7-dichlorofluorene and 1-bromohexane following the procedure of Example 1 as colorless crystals (recrystallized from hexane) in 91 percent yield, melting point 66° C. to 67° C. HPLC analysis shows that the sample is 99 percent or greater pure and the spectral data confirms the title structure.

Workup

  1. customas colorless crystals (recrystallized from hexane) in 91 percent yield, melting point 66° C. to 67° C

Sources & evidence

ORD record
ord-6da0154fb250470eb6f33d4600028697
Source dataset
uspto-grants-2005_05
Patent number
US06900285B2

Reaction notes

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